Abiotic Hydrocarbons Generation Simulated by Fischer-Tropsch Synthesis under Hydrothermal Conditions in Ultra-deep Basins

FTT experiments with water as a hydrogen source and three types of possible carbon sources in the subsurface(diiron nonacarbonyl,siderite and formic acid,representing CO,CO2 and a simple organic acid,respectively)were carried out in this study.Our experimental results showed that n-alkanes with the highest carbon number of C333 were produced when CO was used as a carbon source(series A);a variety of polycyclic aromatic hydrocarbons(PAHs)were detected in series B with CO2 as a carbon source;gaseous hydrocarbons were also detected with formic acid added(series C).The different products in the three series showed that there were different hydrocarbon generation mechanisms and reaction processes with different carbon sources.The generation of long-chain n-alkanes in series A provided experimental support for the formation of abiogenic petroleum underground,which was of significance to early membranes on the Earth.PAHs in series B provide experimental support for the possibility of an abiotic source of reduced carbon on other planets.The carbon isotopes of gaseous hydrocarbons produced by CO exhibited a partial reversed order(δ13C1＜δ13C2＞δ13C3＞δ 13C4＞δ13C5),while the gaseous hydrocarbons produced by CO2 and HCOOH showed a positive order(δ13C1＜δ13C2＜δ13C3＜δ13C4＜δ13C5).Based on these,the alkylene mechanism and the carbonyl insertion mechanism were used to reasonably explain these characteristics.