Electrochemical Synthesis and Structural Characteristics of New Carbon-Based Materials Generated in Molten Salts

This article is devoted to providing a new feasible route to realize carbon dioxide reduction and resource utilization. With the wide electrochemical window, high thermal stability and fast mass transfer rate of molten salt electrolyte, new carbon-based materials can be synthesized on the surface of the inexpensive Fe cathode. EDS (Electron-Dispersive-Spectroscope), SEM (Scanning-Electron-Microscope) and BET (Brunauer-Emmett-Teller) analyzers are selected to detect the critical element, microstructures and specific surface area of the new carbon-based materials generated via electrolysis. It is demonstrated that eutectic carbonates’ electrochemical reduction, ranging from 450 °C to 750 °C prefers to produce carbons with no high-value structure. While carbon products are observed with honeycomb-like and platelet structures at 450 °C with an increase in current density. Additionally, the feedstock CO2 could be converted into carbon-based materials with high value such as high surface area carbon, spherical carbon and cellular porous carbon production by optimizing the electrolysis parameters of temperature, current density and molten salt conformation. This paper shows a viable way for one-pot CO2 utilization and facile production of micro-scale structure carbon materials, in line with the concept of sustainable development.