Quasiliving carbocationic polymerization of isobutylene using FeCl3 as an efficient and water-tolerant Lewis acid: synthesis of well-defined telechelic polyisobutylenes

Mikalai Bohdan,Dmitriy Shiman,Pavel Nikishau,Irina Vasilenko,Sergei V. Kostjuk

Polymer Chemistry（2022）

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摘要

Quasiiving cationic polymerization of isobutylene with dicumyl chloride (DiCumCl)/FeCl3/iPrOH in CH2Cl2/n-hexane 40/60 v/v at –80 °C has been investigated. It was shown that this initiating system afforded well-defined difunctional low...

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关键词

carbocationic polymerization,isobutylene,synthesis,water-tolerant,well-defined

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