Remote Arylalkylation of Unactivated Alkenes via 6- or 7-Membered Nickelacycles with Excellent Diastereofidelity

Junsong Zhao,Linyan Bao, Lin Zhu,Lei Zhao,Luyao Ding,Wei Guan,Chao Wang

Organic Chemistry Frontiers（2022）

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摘要

Herein, we report a nickel-catalyzed remote arylalkylation of unactivated γ,δ- and δ,ε-alkenes in alkenyl carbonyl compounds with arylboronic acids and alkyl halides. Kinetically and thermodynamically disfavored 6- and 7-membered nickelacycles...

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remote arylalkylation,unactivated alkenes

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