Copper(II) complexes containing mixed- chelate ligand, solvatochromism and density functional theory studies

Journal of Molecular Structure(2022)

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摘要
•Two new copper (II) complexes including mixed-chelate ligands were synthesized.•Ligand l acts as tri- and bidentate ligand in different complexes.•One of the complex exhibits solvatochromism.•Statistical analysis showed that salvochromism is due to solvent donor number.•Computational results in three solvents support the proposed solvatochromism.
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关键词
Copper(II),Mixed chelate,Solvatochromism,DFT and TD-DFT calculations,Tridentate ligand,3-chloroacetylacetone
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