Synthesis and structural characterization of metal azolate/carboxylate frameworks incorporating the 1-H-pyrazol-3,4,5-tricarboxylate ligand

Nertil Xhaferaj,Aurel Tăbăcaru,Claudio Pettinari,Kostiantyn V. Domasevitch,Simona Galli

Inorganica Chimica Acta（2022）

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摘要

•Isolation of new metal azolate/carboxylate frameworks with Co(II) and Cd(II).•[Co3(HPZTC)2(H2O)6]·2H2O (MAC-1) features 1-D chains alternating monomeric and dimeric units.•[Co(H2PZTC)(DMF)(H2O)]2 (MAC-2) contains 1-D hydrogen-bonded strands of dimeric units.•[Cd2(PZTC)(H2O)2] (MAC-3) shows a 3-D non-porous network.

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关键词

Pyrazole,Cobalt,Cadmium,Coordination polymers,Metal azolate/carboxylate (MAC) frameworks,Powder X-ray diffraction

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