Use of tetraphenyl (hydroxyl) imidazole for colorimetric detection of iodide: Optical properties, computational characterizations, NBO, QTAIM, and NCI-RDG analyses

Marwa Chaabene,Fakhreddine Zayer,Soumaya Agren,Mahjoub Jabli,Houcine Ghalla,Mohamed Hassen V. Baouab,Rafik Ben Chaâbane

Inorganic Chemistry Communications（2022）

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摘要

•Optoelectronic properties of tetraphenyl (hydroxyl) imidazole were carried out.•Complexation of Imidazole with I− anion was analyzed using experimental UV spectroscopy.•Imidazole has high selectivity towards Iodide over other competitive anions.•Imidazole shows appropriate properties to constitute good I− sensors.

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关键词

Tetraphenyl (hydroxyl) imidazole,Iodide,Chemo sensor,Natural bond orbital,Quantum theory of atoms in molecules,Reduced density gradient

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