Manganese(II) coordination compounds of thiazole-hydrazone based NNN-donor ligands: Synthesis, characterization and catalytic activity

Roghaieh Safikhani-Golboos,Massomeh Ghorbanloo,Rahman Bikas,Roya Sasani,Jan Grzegorz Małecki,Marta S. Krawczyk,Miłosz Siczek

Inorganica Chimica Acta（2022）

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摘要

•Synthesis and characterization of [Mn(L1)2]∙2CH3OH (1) and [Mn(L2)2] (2) where HL1 and HL2 are NNN-donor benzo-thiazole ligand.•Single crystal X-ray structure of two Mn(II) coordination compounds.•Investigation of the catalytic performance of 1 and 2 in olefin oxidation in the presence of TBHP or H2O2 as oxidant.

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关键词

Thiazole,Neutral mononuclear Mn(II) complex,Olefin,Oxidation,TBHP,H2O2

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