Inhomogeneous broadening, narrowing and shift of molecular lines under frequent velocity-changing collisions

Journal of Quantitative Spectroscopy and Radiative Transfer(2022)

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摘要
•We demonstrate that speed-dependent hard-collision profiles collapse into a simple Lorentz profile in the regime dominated by the velocity-changing collisions.•We present simple analytical formulas for the effective width and shift of the Lorentzian, derived from the speed-dependent collisional broadening and shift.
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关键词
Molecular line shapes,Inhomogeneous broadening and shift,Velocity-changing collisions
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