Impact of Sea Breeze on the Transport of Ship Emissions: A Comprehensive Study in the Bohai Rim Region, China

Air pollutants from ship exhaust have a negative impact on air quality in coastal areas, which can be greatly exacerbated by sea breeze circulation. However, our understanding of this issue is still limited, especially in coastal areas with a complex topography and winding coastlines, such as the Bohai Rim region in China. In order to fill this knowledge gap, theWeather Research and Forecast model coupled with the chemistry (WRF/Chem) modeling system was employed to investigate the influence of sea breeze circulation on the transport of PM2.5 emitted by ships from April to September in 2014. The major findings are as follows: (1) The concentration of PM2.5 due to ship emissions was 2.94 mu g/m(3) on days with a sea breeze and 2.4 times higher than on days without a sea breeze in coastal cities in the region. (2) The difference in the contribution of ship emissions during days with a sea breeze and days without a sea breeze decreases with increasing distance from the coastline but remains non-negligible up to 50 km inland. (3) The shape of the coastline, the topographic height of the land area, and the latitude have a significant impact on sea breeze circulation and thus on the transport of ship emissions. (4) The differences in the contribution of ship emissions under days with a sea breeze versus days without a sea breeze were more evident than those under onshore versus alongshore and offshore winds, indicating that sea breeze circulation can cause cyclic accumulation of pollutants and thus reinforce the impact of ship emissions on coastal air quality more than by onshore winds. It should be emphasized that during the switching from sea breeze to a non-sea breeze, the pollutants that have been transported to the land area by sea breeze have not yet been carried back to sea, resulting in the ship contribution value still not significantly reduced even if the wind is a non-sea breeze at that moment. In addition, other factors e.g., emissions, precipitation, and chemistry can also play an important role in the observed trends in this study.