Optimization of Segmented Thermal Barrier Coatings (s-TBCs) for High-Temperature Applications

Hot section components of stationary gas turbines, such as turbine blades and vanes, are coated with thermal barrier coatings (TBCs) to increase the component life. TBCs provide thermal insulation to the metallic components from hot gas in the gas turbines. The TBCs represent high-performance ceramics and are mainly composed of yttria-stabilized zirconia (YSZ) to fulfill the thermal insulation function. The microstructure of the TBCs should be porous to decrease heat conduction. Besides the porous TBCs, the subsequently developed vertically segmented thermal barrier coatings (s-TBCs) feature outstanding thermal durability. For the formation of this segmented coating microstructure, the YSZ should be deposited under high thermal tensile stress during the coating process. Therefore, substrates are heated just before the coating by plasma or in an oven in recent research. In this work, the development of process parameters for s-TBCs produced by atmospheric plasma spray (APS) without pre-heating is presented. Within the experiments, the relevant process parameters, such as plasma gases, powder feed rate, surface speed, and pathway strategy, have been optimized to achieve the segmented coating microstructure with high deposition efficiency by a conventional plasma torch. Furthermore, YSZ powders used in this study are characterized, and the effect of powder characteristics on the coating microstructure is investigated. The coating microstructure in this work aims to achieve the formation of a high number of vertical cracks with a combination of low internal residual stress and high adhesive tensile strength for the s-TBCs.