2D TiVCTx layered nanosheets grown on nickel foam as highly efficient electrocatalysts for the hydrogen evolution reaction

Exploring highly efficient and durable catalysts for the hydrogen evolution reaction (HER) is crucial for the hydrogen economy and environmental protection issues. Numerous studies have now found that transition metal carbide MXenes are ideal candidates as catalysts for the hydrogen evolution reaction. However, MXenes are inclined to easily undergo lamellar structure agglomeration and stacking, which impedes their further applications. Besides, most of the extant research has focused on single transition metal carbides, and the investigation of double transition metal carbide MXenes is rather rare. In this research work, a three-dimensional (3D) TiVCTx-based conductive electrode was constructed by depositing 2D TiVCTx nanosheets on 3D network structured nickel foam (NF) to synthesize a hybrid electrode material (abbreviated as TiVCTx@NF). TiVCTx@NF exhibits efficient electrochemical properties with a low overpotential of 151 mV at 10 mA cm(-2) and a small Tafel slope of 116 mV dec(-1). Benefitting from the open layer structure and strong interfacial coupling effect, compared to the pristine structure, the resulting TiVCTx@NF has greatly increased active sites for the hydrogen evolution reaction (HER) and encounters less resistance for charge transfer. In addition, TiVCTx@NF exhibits better stability in long-term acidic electrolytes. This work provides a tactic to prepare three-dimensional network electrode materials and broadens the application of single transition metal carbide MXenes as water splitting electrodes in the HER, which is beneficial to the application of noble metal-free electrocatalysts.