Different conformations and packing motifs in the crystal structures of four thiophene–carbohydrazide–pyridine derivatives
Acta Crystallographica Section E Crystallographic Communications(2022)
摘要
The crystal structures of four thiophene–carbohydrazide–pyridine derivatives, viz. N′-[(E)-pyridin-3-ylmethylidene]thiophene-2-carbohydrazide, C11H9N3OS, (I), N′-[(E)-pyridin-2-ylmethylidene]thiophene-2-carbohydrazide, C11H9N3OS, (II), N-methyl-N′-[(E)-pyridin-2-ylmethylidene]thiophene-2-carbohydrazide, C12H11N3OS, (III) and N′-[(E)-pyridin-2-ylmethylidene]-2-(thiophen-2-yl)ethanohydrazide, C12H11N3OS, (IV) are described. The dihedral angles between the thiophene ring and the pyridine ring are 21.4 (2), 15.42 (14), 4.97 (8) and 83.52 (13)° for (I)–(IV), respectively. The thiophene ring in (IV) is disordered over two orientations in a 0.851 (2):0.149 (2) ratio. Key features of the packing include N—H⋯Np (p = pyridine) hydrogen bonds in (I), which generate C(7) chains propagating in the [001] direction; N—H⋯Np links also feature in (II), but in this case they lead to C(6) [001] chains; in (IV), classical amide (C4) N—H⋯O links result in [010] chains; in every case adjacent molecules in the chains are related by 21 screw axes. There are no classical hydrogen bonds in the extended structure of (III). Various weak C—H⋯X (X = O, N, S) interactions occur in each structure, but no aromatic π–π stacking is evident. The Hirshfeld surfaces and fingerprint plots for (I)–(IV) are compared.
更多查看译文
关键词
crystal structure,thiophene,carbohydrazide,pyridine
AI 理解论文
溯源树
样例
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要