Facile Synthesis of CoSe/Co3O4-CNTs/NF Composite Electrode for High-Performance Asymmetric Supercapacitor

MATERIALS(2022)

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摘要
Electrode materials are key factors for supercapacitors to endow them with excellent electrochemical properties. Here, a novel hybrid structure of a CoSe/Co3O4-CNTs binder free composite electrode on nickel foam was prepared via a facile flame method, followed by an electrodeposition process. Benefitting from the synergetic effects of the multicomponent (with low resistances of 1.542 omega cm(2) and a moderate mesoporous size of 3.12 nm) and the enlarged specific surface area of the composite material (77.4 m(2) g(-1)), the CoSe/Co3O4-CNTs composite electrode delivers a high specific capacitance of 2906 F g(-1) at 5 mV s(-1) with an excellent rate stability. The fabricated CoSe/Co3O4-CNTs/NF//AC ASC exhibits a high energy density of 43.4 Wh kg(-1) at 0.8 kW kg(-1) and a long cycle life (92.7% capacitance retention after 10,000 cycles).
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关键词
CoSe, Co3O4-CNTs composite electrode, flame method, ultra-high specific capacitance, long cycle life, asymmetric supercapacitor
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