High performance self-assembled nano-chlorapatite in the presence of lactonic sophorolipid for the immobilization of cadmium in polluted sediment.

A novel lactonic sophorolipid (LS) self-assembled nano-chlorapatite (LS-nClAP) was prepared for the immobilization of severe cadmium (Cd) in sediment. The experimental results indicated that the introduction of LS not only improved the dispersed performance of chlorapatite, but also brought massive hydroxyl and carboxyl groups, which significantly improved the immobilization efficiency of Cd and reduced its eco-toxicity in sediment. LS can significantly increase the effective utilization rate of phosphorus in chlorapatite, and reduce the content of available phosphorus (AP) by half after remediation compared with ClAP. Additionally, the participation of LS possessed a significant impact on the enzyme activities in the sediment, especially for urease, which was closely related to the effective stability of Cd and the introduction of LS. All experimental results of this study provided new insights into the possible effects of Cd immobilization by chlorapatite in contaminated sediments, demonstrating great application potential for sediment remediation in the future.