Reexamining the heavy-atom-effect: The universal heavy-atom-induced fluorescence enhancement principle for through-space conjugated AIEgens

Chemical Engineering Journal(2023)

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摘要
Classic heavy-atom effect was reexamined from a completely fresh perspective of emerging AIEgens, and a universal heavy-atom-induced fluorescence enhancement principle suited for most AIEgens was proposed, which prompts the redefinition of heavy-atom effect depending on distinct conjugation patterns and also provides an effective strategy to achieve highly efficient AIEgens.
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关键词
Heavy-atom effect,Photophysical principle,Aggregation-induced emission,Tetraphenylethylene,Through-space conjugation,Fluorescence enhancement
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