Dinuclear Silver(I) and Gold(I) Complexes with Chiral Oxazoline-NHC Ligands

Hoffmann Marie,Samuel Dagorne,Patrick Pale,Blanc Aurélien,Pierre de Frémont

Journal of Organometallic Chemistry（2022）

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摘要

The coordination chemistry of chiral NHC-oxazoline bidentate ligands was investigated with silver(I) and gold(I), yielding stable dinuclear cationic complexes in good yields via N-coordination of the oxazoline heterocycle. After full characterization of these complexes, the reactivity in homogeneous catalysis and under oxidative conditions was studied.(c) 2022 Elsevier B.V. All rights reserved.

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关键词

NHC ligands,Chiral oxazoline,Silver,Gold,Dinuclear complexes,Transmetalation,X-ray diffraction

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