SmI2-mediated intermolecular addition-elimination of piperidine and pyrrolidine N-alpha-radicals with arylacetylene sulfones

Chang-Hong Liu,Jia-Ming Guo,Xin Li,Jian-Ting Sun,Bang-Guo Wei,Chang-Mei Si

Chemical Communications（2022）

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摘要

An efficient approach to access alpha-arylacetylene-substituted pyrrolidine and piperidine derivatives has been developed through a samarium diiodide-mediated addition-elimination process of pyrrolidine and piperidine N-alpha-radicals with arylacetylene sulfones.

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