An in situ spectroelectrochemical study of the dimeric phthalocyanines [(SiPc)2O][OSiHx3]2, [(SiPc)2O][OSiHx3]2+, and [(SiPc)2O][OSiHx3]22+

Evgenia Dmitrieva, Benjamin W. Sturtz,Yang Yang,Ping Zhang, Lothar Dunsch,Malcolm E. Kenney

Electrochemistry Communications（2021）

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摘要

•[(SiPc)2O][OSiHx3]2 oxidizes to form [(SiPc)2O][OSiHx3]2+.•[(SiPc)2O][OSiHx3]2+ oxidizes to form [(SiPc)2O][OSiHx3]22+.•CV, ESR and NIR data show strong interactions between rings.

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关键词

Phthalocyanines,Dimer,Electron spin (paramagnetic) resonance (ESR/EPR) spectroscopy,Spectroelectrochemistry,Radical cation

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