Chemoselective Chan-Lam coupling by directly using copper powders via mechanochemical metal activation for catalysis

Weijia Shi,Yu Shi,Minling Xu,Gang Zou,Xin-Yan Wu

Molecular Catalysis（2022）

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摘要

•Direct use of commercial copper powders.•Dramatic solvent effects of alcohols.•Amidocopper(I) identified as catalytically active species.•High chemoselectivities with respect to both counterparts.•Unique effects of acetate co-catalysts.

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关键词

Mechanochemistry,Ball-milling,Chan-Lam coupling,Copper,Carbon-nitrogen bond formation

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