Mechanisms of electrochemical magnesium (de)alloying of Mg-Sn and Mg-Pb polymorphs

Clement Pechberty, Antoine Klein,Bernard Fraisse,Lorenzo Stievano,Romain Berthelot

Journal of Magnesium and Alloys（2022）

引用 6|浏览3

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摘要

•Mg-Sn and Mg-Pb intermetallics are prepared by high-energy ball-milling.•Tuning the milling time allows to obtain cubic Mg2Sn and Mg2Pb or non-cubic Mg∼2Sn and Mg∼2Pb polymorphs.•Intermetallics are investigated as active material in Mg-batteries by operando X-ray diffraction.•The alloying process favors the formation of the cubic alloy for both tin and lead.

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关键词

Magnesium batteries,Alloy electrode,Mechanochemistry,Operando X-ray diffraction

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