Synthesis and characterization of N-TMS-2-pyridinamine dimethyl-aluminum: A dormant precursor

Inorganic Chemistry Communications（2022）

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摘要

•N-TMS-2-pyridinamine dimethyl-aluminum has the property of converting the dormant state(dimer) to the better volatile active state(monomer) by adjusting its configuration by temperature, which can provide a case study for the development of dormant precursors.•The enthalpy of evaporation(ΔHvapour) is applied to the study of N-TMS-2-pyridinamine dimethyl-aluminum(dimer) depolymerization.

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关键词

Precursor,Dimethyl-aluminum,Thermodynamic properties

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