2H-5,10,15,20-tetrakis(3-aminophenyl)porphyrin films: Electrochemical formation and catalyst property testing

Sergey M. Kuzmin,Svetlana A. Chulovskaya,Olga A. Dmitrieva,Nugzar Z. Mamardashvili,Oskar I. Koifman,Vladimir I. Parfenyuk

Journal of Electroanalytical Chemistry（2022）

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摘要

•Tetra(3-aminophenyl)porphyrin films were formed via superoxide-assisted method;•Ab initio applies for adsorption energy analysis on the catalytic site;•3-aminophenyl porphyrin based films show promising ORR activity;•Calculations indicate on the same ORR mechanism as experiments.

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关键词

Superoxide assisted deposition,Porphyrin,Oxygen reduction reaction,Ab initio calculation,Electro catalysis

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