Solvent-assisted ligand exchange as a post-synthetic surface modification approach of Zn-based (ZIF-7, ZIF-8) and Co-based (ZIF-9, ZIF-67) zeolitic frameworks for energy storage application

Journal of Molecular Liquids(2022)

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摘要
•Two Zn-based and two Co-based MOFs have synthesized by mechanical method.•Solvent assisted ligand exchanged used for surface modification of each ZIFs.•ZIF67@ZIF-9 was selected as best electrode with specific capacitance of 300F/g.•Asymmetric device reached to capacitance retention of 89 % after 3,000 cycles.
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关键词
ZIF,Ligand exchange,Mechanochemical synthesis,Supercapacitor,Energy storage
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