Humic acid coupled with coal gasification slag for enhancing the remediation of Cd-contaminated soil under alternated light/dark cycle

In this study, the synthesis of a coal gasification slag-humic acid (SA) hybrid was purposed for the remediation of cadmium (Cd)-contaminated soil. In order to investigate the effect of SA on the Cd-contaminated soil and plant growth, a series of experiments were carried out under different illumination condition. The results showed that the SA has some the photocatalytic activity, and adding 10 wt% of SA to the soil could obviously improve the soil fertility and decrease the mobility of Cd in the soil under alternated light/dark cycle (12L/12D); the content of the residual fraction in the SA-amended soil reached 69.5%, and the Cd decreasing rates for the leaf, stem, and root of Artemisia ordosica were near 100%, 91.3%, and 75.3%, respectively. Characterizations of amendments suggested that the synergistic effect of precipitation and surface complexation played a major role in the remediation of Cd-contaminated soil. Graphical abstract