Phase change in GeTe/Sb2Te3 superlattices: Formation of the vacancy-ordered metastable cubic structure via Ge migration

Applied Surface Science(2022)

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摘要
In this study a large-area phase change was performed using optical laser pulsing to demonstrate the formation of metastable face-centered cubic GeSbTe blocks in the reset state of iPCM resulting from the Ge atom rearrangement to the pre-existing vacancy layers, which will be the basis for the phase-transition mechanism of next generation non-volatile memory devices.
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关键词
Superlattice,GeTe/Sb2Te3 thin film,Epitaxial thin films,Metavalent bonding,Metal-to-insulator transition,Interfacial phase-change materials,Reversible bond-switching,Phase-change mechanism,Vacancy layer,DFT calculation
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