Effect of chromium and boron incorporation methods on structural and catalytic properties of hierarchical ZSM-5 in the methanol-to-propylene process
Journal of Industrial and Engineering Chemistry(2022)
摘要
•Hierarchical M-ZSM-5 (M = Cr, B) were synthesized by CTAB and F127 mesoporogens.•Introduction of metals was performed by impregnation and hydrothermal synthesis.•Preferred growth orientation of zeolites affected their catalytic performance.•Cr (VI) species and OH groups were predominant in the impregnated Cr-ZSM-5.•The best performance in the MTP process was obtained for impregnated B-ZSM-5.
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关键词
Hierarchical,Chromium-ZSM-5,Boron-ZSM-5,Impregnation,Preferred orientation
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