Selective entrapment of thorium using a three-dimensional covalent organic framework and its interaction mechanism study

Xiaojuan Liu,Songtao Xiao,Tiantian Jin,Feng Gao,Ming Wang,Yanan Gao,Wei Zhang,Yinggen Ouyang,Guoan Ye

Separation and Purification Technology（2022）

引用 6|浏览5

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摘要

•Three-dimensional COFs was first introduced into the field of Th (IV) separation.•The adsorption capacity of COF-DL229 is higher than reported two-dimensional COF.•COF-DL229 exhibits excellent selectivity for Th (IV) compared to other materials.•The interaction mechanism was explored by characterizations and DFT calculations.

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关键词

Three-dimensional covalent organic frameworks,Thorium,Selective entrapment,Coordination interaction,DFT calculations

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