Effect of ion interactions on the Raman spectrum of NO3−: Toward monitoring of low-activity nuclear waste at Hanford

Stefani Kocevska,Giovanni Maria Maggioni,Steven H. Crouse,Rupanjali Prasad,Ronald W. Rousseau,Martha A. Grover

Chemical Engineering Research and Design（2022）

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摘要

•Ion interactions in sodium salt mixtures result in a nitrate peak shift in Raman.•Cation concentration is a good predictor of the nitrate peak shift in binary and ternary systems.•Nitrate peak shifting is present in spectra of low-activity nuclear waste simulants.

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