A ring expansion approach to N-oxy-2,5-diketopiperazines

Amy C. Jackson,James T. Olsen, Sasha Sundstrom,Kyle M. Lambert,John L. Wood

Tetrahedron Letters（2022）

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摘要

A ring expansion of tetramic acids (pyrrolidine-2,4-diones) to N-oxy-2,5-diketopiperazines (DKPs) is described. This method allows for the facile and late-stage construction of the hydroxamic acid moiety and can thereby serve as a general method for accessing N-oxy-2,5-DKP natural products.

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