Synthesis, crystal structure and spectroscopic characterization of new anionic iridium(III) complexes and their interaction with biological targets

Joanna Masternak, Agnieszka Gilewska,Mateusz Kowalik,Katarzyna Kazimierczuk,Jerzy Sitkowski, Karol Okła,Joanna Wietrzyk,Barbara Barszcz

Polyhedron（2022）

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摘要

A new anionic Ir(III) complexes with κ2N,N’-2,2′-biimidazole (1) or 2-(2′-pyridyl)bezminidazole (2) have been synthesized. The Ir(III) slightly distorted octahedral geometry confirmed SC-XRD analysis. The strong hydrogen bonds have significant impact on 2D (1) and 3D (2) crystal structures. The complexes exhibit desired binding affinity to DNA and HSA molecular targets.

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关键词

Anionic iridium(III) complexes,Molecular and crystal structure,Hydrogen bonds,HSA/DNA interactions,Cytotoxicity

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