Green synthesis of cyclohexanone to adipic acid over Fe–W oxides incorporated mesoporous carbon support

Catalysis Communications(2022)

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摘要
We have prepared iron and tungsten oxides incorporated mesoporous carbon (MC) catalysts using a simple hydrothermal methodology with different carbon sources, and the catalytic performance was investigated for cyclohexanone oxidation. An adequate amount of metal oxide loading has displayed a key role in the selective catalyst for adipic acid (AA) synthesis. The MC catalyst has shown its prime activity under the influence of redox properties of W5+/W6+ and Fe2+/Fe3+ as promoters. The 10%Fe 90%W-MC fructose as a carbon source catalyst has provided its best selectivity of 87% for AA at 120 °C.
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关键词
Mesoporous carbon,Redox center,Liquid phase oxidation,Adipic acid
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