Iron(III) complexes of pyrrolidine and piperidine appended tridentate 3N donor ligands as models for catechol dioxygenase enzymes

Thukkaiyandi Shapterhasmi, Narasimman Palani,Marappan Velusamy, Nattamai S.P. Bhuvanesh,Karuppasamy Sundaravel,Shanmugam Easwaramoorthi

Inorganica Chimica Acta（2022）

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摘要

•Fe(III) complexes (1–6) of 3N donor ligands were isolated and characterised.•Complexes 1 and 3 possess a distorted octahedral geometry.•All the complexes elicit major amounts of extradiol products in acetonitrile.

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关键词

Iron(III) complexes,tridentate 3N ligands,Pyrrolidine and piperidine donor,Catechol cleavage,Extradiol product

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