Reactivity of B(C6F5)3 towards glycidol: The formation of branched cyclic polyglycidol structures

Mohammed Ali Al Assiri, Eric Gomez Urreizti,Carlo Andrea Pagnacco,Estibaliz Gonzalez de San Roman,Fabienne Barroso-Bujans

European Polymer Journal（2022）

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摘要

•Branched cyclic polyglycidol is generated in gram amounts in a single step.•Significant chain growth occurs at high monomer conversion in bulk conditions.•Addition of small volumes of solvents conduct to changes in the molecular weight.•The glass transition temperature is dominated by branching.

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关键词

Polyglycidol,Polyglycerol,Cyclic,Ring,Ring expansion polymerization

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