On the CN⁻⋯K coordination modes in K_n[M⁶⁻ⁿ(CN)₆]·xH₂O: first evidence of CN⁻⋯K electron-deficient bonding

Manuel Avila,Lucero Torres,Ana L. Montero-Alejo,Leslie Reguera,Edilso Reguera

Dalton Transactions（2021）

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摘要

The occurrence of electron-deficient bonding (3c–2e or 4c–2e) between the CN− ligand N end and K+ is reported for the structures of Kn[M6−n(CN)6]·xH2O. The atypical N-bipodal and N-tripodal coordination CN−···K+ agrees with these bonding models.

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On the CN−⋯K coordination modes in Kn[M6−n(CN)6]·xH2O: first evidence of CN−⋯K electron-deficient bonding

On the CN⁻⋯K coordination modes in K_n[M⁶⁻ⁿ(CN)₆]·xH₂O: first evidence of CN⁻⋯K electron-deficient bonding