Polar derivatives of [closo-1-CB₉H₁₀]⁻ and [closo-1-CB₁₁H₁₂]⁻ anions as high Δε additives to a nematic host: a comparison of the CH₂CH₂ and COO linking groups

Rafał Jakubowski,Jacek Pecyna,Muhammad O. Ali,Anna Pietrzak,Andrienne C. Friedli,Piotr Kaszyński

Dalton Transactions（2021）

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摘要

Liquid crystalline pyridinium zwitterions of [closo-1-CB9H10]− perform better as polar potential components of LCD materials than the sulfonium or [closo-1-CB11H12]− analogs on the basis of solubility and Maier–Meier analysis.

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Polar derivatives of [closo-1-CB9H10]− and [closo-1-CB11H12]− anions as high Δε additives to a nematic host: a comparison of the CH2CH2 and COO linking groups

Polar derivatives of [closo-1-CB₉H₁₀]⁻ and [closo-1-CB₁₁H₁₂]⁻ anions as high Δε additives to a nematic host: a comparison of the CH₂CH₂ and COO linking groups