Enabling Cyclization Strategies through Carbonyl-Ylide-Mediated Synthesis of Malonate Enol Ethers.

Júlia Viñas-Lóbez,Guillaume Levitre,Adiran de Aguirre,Céline Besnard,Amalia I. Poblador-Bahamonde,Jérôme Lacour

ACS organic & inorganic Au（2021）

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摘要

Malonate enol ethers are afforded in one step by condensation of cyclic ketones with α-diazomalonates under [CpRu(CHCN)][BAr] catalysis. The dual reactivity of these 2-vinyloxymalonates can be used to expand the classical range of cyclizations derived from carbonyl ylide intermediates.

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关键词

Carbonyl ylide reactivity, CpRu catalysis, Diazo decomposition, Enol ethers, Malonate

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