Design of Fe^III–Ln^III binuclear complexes using compartmental ligands: synthesis, crystal structures, magnetic properties, and ab initio analysis

Alexandru Topor,Dan Liu,Catalin Maxim,Ghenadie Novitchi,Cyrille Train,Zeid A. AlOthman,Abdullah A. S. Al-Kahtani,Liviu Ungur,Le Tuan Anh Ho,Liviu F. Chibotaru,Marius Andruh

Journal of Materials Chemistry C（2021）

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摘要

Rare examples of phenoxido-bridged FeIII–LnIII binuclear complexes are synthesized, and their dynamic and static magnetic properties are rationalized by ab initio calculations.

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Design of FeIII–LnIII binuclear complexes using compartmental ligands: synthesis, crystal structures, magnetic properties, and ab initio analysis

Design of Fe^III–Ln^III binuclear complexes using compartmental ligands: synthesis, crystal structures, magnetic properties, and ab initio analysis