Na_1.5Rb_0.5PO₃F·H₂O: synthesis, properties, and stepwise reconstruction of the hydrogen bond network

Xin-Rui Yang,Xin Liu,Zujian Wang,Xue-Bin Deng,He-Jie Lu,Yu-Jia Li,Xifa Long,Ling Chen,Li-Ming Wu

Inorganic Chemistry Frontiers（2021）

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摘要

The precise substitution of NH4+ with Na+/Rb+ cations in NPF·H2O leads to a stepwise reconstruction of the hydrogen bond networks from NPF·H2O, NNPF·H2O to NRPF·H2O, giving rise to the symmetry and optical property tunings.

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Na1.5Rb0.5PO3F·H2O: synthesis, properties, and stepwise reconstruction of the hydrogen bond network

Na_1.5Rb_0.5PO₃F·H₂O: synthesis, properties, and stepwise reconstruction of the hydrogen bond network