Multi-scale chemo-mechanical evolution during crystallization of mixed conducting SrTi_0.65Fe_0.35O_3−δ films and correlation to electrical conductivity

Haley B. Buckner,Qing Ma,Joshua Simpson-Gomez,Emily J. Skiba,Nicola H. Perry

Journal of Materials Chemistry A（2022）

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摘要

Crystallization of a perovskite mixed conductor is coupled to oxidation, which drives defect chemistry, ion coordination, polyhedra alignment, hierarchical microstructure, and property evolution – including a boost to electrical conductivity.

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Multi-scale chemo-mechanical evolution during crystallization of mixed conducting SrTi0.65Fe0.35O3−δ films and correlation to electrical conductivity

Multi-scale chemo-mechanical evolution during crystallization of mixed conducting SrTi_0.65Fe_0.35O_3−δ films and correlation to electrical conductivity