Planar Blatter radicals through Bu₃SnH- and TMS₃SiH-assisted cyclization of aryl iodides: azaphilic radical addition

Paulina Bartos,Małgorzata Celeda,Anna Pietrzak,Piotr Kaszyński

Organic Chemistry Frontiers（2022）

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摘要

Radical chain cyclization of aryl iodides provides an efficient synthesis of planar Blatter radicals, and, for the first time, access to functionalized sulphur-containing analogues.

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Planar Blatter radicals through Bu3SnH- and TMS3SiH-assisted cyclization of aryl iodides: azaphilic radical addition

Planar Blatter radicals through Bu₃SnH- and TMS₃SiH-assisted cyclization of aryl iodides: azaphilic radical addition