Cation disorder and thermoelectric properties in layered ternary compounds MBi₂Te₄ (M = Ge, Sn)

Journal of Materials Chemistry C（2022）

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摘要

Atomic-scale investigation of layered thermoelectric materials reveals the positional disordering of heterovalent cations (Ge+2/Bi+3 and Sn+2/Bi+3) in the crystal lattice (the 3a Wyckoff site) of ternary MBi2Te4 (M = Ge, Sn) compounds.

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Cation disorder and thermoelectric properties in layered ternary compounds MBi2Te4 (M = Ge, Sn)

Cation disorder and thermoelectric properties in layered ternary compounds MBi₂Te₄ (M = Ge, Sn)