Structural and Dielectric Properties of Ba-Doped BNT Ceramics

In this study, lead-free Ba-doped ((Bi(0.5)Na0.5)TiO3 ceramics were synthesized by the conventional solid-state reaction method and characterized by X-ray diffraction technique, which indicates the pure crystalline nature of ceramics with ABO3 symmetry. The splitting in the peaks reveals that the ceramics with x = 0.10 and 0.30 are well in Morphotrophic Phase Boundary where rhombohedral and tetragonal phases co-exist. The scanning electron microscope images show that the average grain size of the ceramics increases with an increase in the Ba concentration. Dielectric properties of pure and Ba-doped ((Bi(0.5)Na0.5)TiO3ceramics measured by LCR meter in the frequency range of 1 k Hz – 1 M Hz shows the decrease in the value of dielectric constant with an increase in frequency. εmax = 5563 was obtained at x = 0.30 with TC = 300 °C at the frequency of 1 k Hz, whereas σ (f) curves were found to be merging at a high value of frequency and temperature regions.