Photocatalyzed Functionalization of Alkenoic Acids in 3D-Printed Reactors
CHEMSUSCHEM(2022)
摘要
The valorization of alkenoic acids possibly deriving from biomass (fumaric and citraconic acids) was carried out through conversion in important building blocks, such as gamma-keto acids and succinic acid derivatives. The functionalization was carried out by addition onto the C=C double bond of radicals generated under photocatalyzed conditions from suitable hydrogen donors (mainly aldehydes) and by adopting a decatungstate salt as the photocatalyst. Syntheses were performed under batch (in a glass vessel) and flow (by using 3D-printed reactors) conditions. The design of the latter reactors allowed for an improved yield and productivity.
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关键词
carboxylic acids, 3D-printed reactors, flow chemistry, photocatalysis, radical reactions
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