Rhodium(II)-Catalyzed C(sp(3))-H Diamination of Arylcyclobutanes

Xinyu Liu,Zhifan Wang,Qiwei Wang,Yuanhua Wang

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION（2022）

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摘要

Activated by multiple consecutive oxidative radical-polar crossover and desaturation processes, the selective diamination of arylcyclobutanes, which is difficult to perform by classical metallonitrene C-H insertion, was achieved in a short time by rhodium(II) catalysis using N-fluorobenzenesulfonimide (NFSI) as the oxidant and nitrogen source.

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关键词

Amination, C-H Functionalization, Cyclobutanes, Hydrogen Atom Transfer, Rhodium

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