Solvatochromic Parameters of the Polarity of Binary Carbon Dioxide–Alcohol Systems at Elevated Temperatures and Pressures

T. E. Skrebets,A. D. Ivakhnov,K. G. Bogolitsyn, K. S. Sadkova

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A（2021）

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摘要

Values of Kamlet–Taft solvatochromic parameters and Dimroth–Reichardt energy are determined via UV spectroscopy for carbon dioxide–alcohol (ethanol, isopropanol) mixtures at temperatures of 295−353 K and pressures of 100−300 atm in a wide range of component ratios.

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关键词

carbon dioxide, cosolvent, ethanol, isopropanol, solvatochromic parameters, Dimroth-Reichardt energy

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