Monodispersed SWNTs Assembled Coating Layer as an Alternative to Graphene with Enhanced Alkali-ion Storage Performance
Chinese Journal of Structural Chemistry(2022)
摘要
Graphene coating is commonly used to improve the performance of electrode materials, while its steric hindrance effect hampers fast ion transport with compromised rate capability. Herein, a unique single-walled carbon nanotubes (SWNTs) coating layer, as an alternative to graphene, has been developed to improve the battery behavior of iron-based anodes. Benefiting from the structure merits of mesoporous SWNTs layer for fast electron/ion transport and hollow Fe3O4 for volume accommodation, as-prepared Fe3O4@SWNTs exhibited excellent lithium storage performance. It delivers a high capacity, excellent rate capability, and long lifespan with capacities of 582 mA·h·g-1 at 5 A·g-1 and 408 mA·h·g-1 at 8 A·g-1 remained after 1000 cycles. Such performance is better than graphene-coated Fe3O4 and other SWNT-Fe3O4 architectures. Besides, SWNTs coating is also used to improve the sodium and potassium storage performance of FeSe2. The kinetics analysis and ex-situ experiment further reveal the effect of SWNTs coating for fast electron/ion transfer kinetics and good structure stability, thus leading to the superior performance of SWNTs-coated composites.
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关键词
single-walled carbon nanotubes,graphene,Fe3O4,FeSe2,alkali-ion batteries
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