Orientation in large-area semiconducting 2-amino-anthracene thin films fabricated by dynamic floating film transfer method
THIN SOLID FILMS(2022)
摘要
In organic electronics, fabrication of stable, soluble, and uniform thin films of large surface area is highly important for a wide range of organic device applications. However, these objectives are difficult to achieve when using organic liquid crystalline molecules. This work focuses on a molecular organic material synthesized in our lab which was used to fabricate large-area thin films by applying the recently developed ribbon-shaped floating film transfer method (FTM). After establishing the most optimal casting parameters, organic molecule thin films of large surface area (up to 15 cm in length and 2 cm in width) were obtained. Subsequent polarized optical microscopy and atomic force microscopy investigations confirmed that film morphology and texture was uniform. Further, UV spectroscopy measurements using a polarizer were performed to study the pi-pi conjugation, indicating that the films exhibited optical anisotropy, as a Dichroic Ratio (DR) of 3.8 was obtained, with a 10 nm redshift in parallel FTM relative to the spin-coating method.
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关键词
Organic semiconductor, Molecular orientation, Floating film transfer method, Polarized absorption, Liquid crystal
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