Synthesis, crystal structure and electrochemical properties of a new methylammonium sodium decavanate salt Na3(CH3NH3)3[V10O28].(CH3NH2).14H2O

Journal of Molecular Structure(2022)

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摘要
•A new hybrid decavanadate type anion with mixed organic/inorganic counterions is synthetized.•The compound consists of the non-protonated decavanadate anion stabilized with a methylammonium/sodium cations.•The investigation of electrochemical properties shows two consecutive one-electron VV → VIV reductions.
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关键词
Polyoxometalate,Decavanadate,Electrochemical property
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