An iron supramolecular compound containing terpyridine polycarboxylic acid for high performance lithium-ion batteries

Haitao Zhu,Shengyun Liao, Rongrong Bian,Boya Su,Xiaohui Ding,Mengying Li,Shuxian Ge,Haode Zhang,Qiang Liu

Inorganica Chimica Acta（2022）

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摘要

•A novel coordination compound [Fe(HTPYPA)2] was synthesized and characterized.•The Fe(II) centers greatly increase the capacity of organic polycarboxylic acids.•The discharged capacity of Fe(HTPYPA)2 is up 650 mAh g−1 at current density of 100 mA g−1.•The synergistic effect between π-conjugated tripyridine-based polycarboxylic groups and Fe(II) may explain the good electrochemical performance.

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关键词

Supramolecular compound,Terpyridine polycarboxylic acid,π-Conjugated,Discharge capacity,Carboxylate electrode

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